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Phase relations in the MORB+H2O system from 10 to 20 GPa
@@@@@@@@@Kazuaki Okamoto (Univ. Milan)
I conducted ultrahigh P experiments in the
MORB+ H2O system at T lower than 1200 C to decipher the fate of
oceanic crust in the coldest slab at the mantle transition zone. The result is
as follows. The jadeite eclogite facies (Grt+ Jd) is bounded at the lower P
side by the omphacite eclogite facies (Grt+omp). The boundary runs between 13
and 14 GPa, at 700 C, and between 14 and 15 GPa, at 900 and 1100 C. The
jadeite eclogite facies is bounded at high P side by CaPv garnetite facies (Grt+CaPv).
The boundary runs between 900 and 1000 C,
at P = 19 GPa,
between 16 and 17 GPa, at 800 C, and
between 18 and 19 GPa, at 900 C.
It is
enlarged omphacite dissolution in garnet within 1 GPa of pressure range,
between 14 and 15 GPa. Over 17 GPa, decrease of dissolution of pyroxene
component into garnet is caused by enlargement of Na dissolution of hollandite.
At 18 GPa, Ca-perovskite is exsolved from garnet reached its maximum Ca content
(Gasparik, 1996).
Estimated H2O content in subducting
oldest oceanic crust indicates a sudden decrease of water content at 15 GPa.
This is simply caused by decrease of CaEs component in clinopyroxene. At
further higher pressures than 19 GPa, stishovite, and new hydrous phase
identified by Otani et al. (2001) would be water container.
