No.277 Geodynamics Seminar
"Phase stability, compressiblity and thermal expansion of Ca-rich
aluminosilicate CaAl4Si2O11 at high-P,T conditions "
Dr. Steeve Greaux
(Global COE Postdoctral Fellow, GRC)
4:30 pm 〜, 19 November 2010
Meeting room "Glova", 4 floor, Integrated Research
Building
Abstract
The Earth's internal dynamics drive materials from its surface
into its deep interior, where those materials are believed to be recycled through various high-pressure and high-temperature
processes including chemical and structural transformations but also melting in the deep mantle. Therefore, the HP-HT behaviors
of sediments and crustal materials are of interest as they are candidate components for creating compositional and density
heterogeneities in the Earth's mantle. In this regard, the CAS phase is a Ca-rich aluminosilicate that has been observed in
the decomposition products of continental crust, basaltic compositions and anorthite system at high-P,T conditions
(Irifune et al., 1994; Gautron et al., 1996; Hirose and Fei, 2002). Naturally occurring CAS phase has also been
discovered in shocked martian meteorites (Beck et al., 2004). Thus, this phase might be an important constituent
mineral of sediments and basalts subducted in the deep mantle.
Here, we examinate the HP-HT behaviors of the CAS phase up to the P,T conditions of the lowermost transition zone
by energy dispersive X-ray diffraction, using a Kawai-type multi-anvil press apparatus coupled with synchrotron
radiation in SPring-8 (Japan). The high-P,T phase stability and pressure-volume-temperature relations of the
CAS phase with the composition of CaAl4Si2O11 were examinated in situ up to 24 GPa and 2100 K. The present
data enables the accurate estimate of density of the CAS phase in the deep mantle for various temperature profiles (i.e. adiabatic mantle or cold slab geotherms).
For inquiry:Taku Tsuchiya TEL:(089)927-8198
E-mail takut@sci.ehime-u.ac.jp
